The aim of the present article is to expose a new method based on TGA-FTIR coupling to quantify the different steps of the thermal degradation of EVA in the presence of HNT. Moreover, this quantification of the thermal degradation was also correlated to the color change. EVA/HNT composites were processed with different processing conditions: solvent casting in THF or melt blending at different temperatures. The HNT fillers content (from 10 wt% up to 30 wt%) and the melt blending temperature (at 130 °C, 150 °C, 170 °C and 190 °C) were varied. The thermal degradation of EVA in the presence of HNT presents three noticeable steps as evidenced by TG analysis: i) P1, which was identified as the catalytic degradation of vinyl acetate (VA) part of EVA occurring during the heating ramp (around 250 °C), ii) P2, which is the main degradation of VA (around 350 °C) and iii) P3, which is the degradation of the polyethylene chain of EVA (around 500 °C). Nevertheless, in the case of melt blended EVA/HNT composites, macroscopic changes (strong smell and browning color) indicate a thermal degradation occurring during the melt blending process, namely P0. FTIR-TGA coupling allows to quantify the contribution of P0, P1 and P2 (thermal degradation of VA units of EVA) using Gram Schmidt curves of released acetic acid gas which are obtained from the Cdouble bondOac. band of acetic acid at 1795 cm−1. The contribution of each thermal degradation step of the VA part of EVA (named P0 to P2) was then quantified and reported as A0 to A2, respectively. The blending process (solvent or melt) such as the HNT fillers content and the melt blending temperatures have a significant influence on the EVA thermal degradation catalyzed by HNT. For example, it was shown that the thermal degradation of VA units occurring during the processing of EVA+ 30HNT composite (named A0 and catalyzed by the HNT) was of 40% for melt blending process (at 170 °C), whereas it was close to 0% for solvent casting process. Moreover, the macroscopic changes were evaluated by color measurements and an interesting correlation could be made between A0 and ΔE* which is the total color deviation. When a significant catalytic effect, during the melt process was observed (A0 values higher than 5%), the total color deviation ΔE* was increased linearly with A0. Finally, in order to avoid the catalytic effect of HNT on the EVA thermal degradation, a functionalization strategy has been developed with an organosilane leading to the suppression of P1, the catalytic degradation of VA in TG analyses.