Calcium and Aluminium-Based Fillers as Flame-Retardant Additives in Silicone Matrices. II. Analyses on Composite Residues from an Industrial-Based Pyrolysis Test - IMT Mines Alès Accéder directement au contenu
Article Dans Une Revue Polymer Degradation and Stability Année : 2011

Calcium and Aluminium-Based Fillers as Flame-Retardant Additives in Silicone Matrices. II. Analyses on Composite Residues from an Industrial-Based Pyrolysis Test

Résumé

The second part of this series, devoted to the study of model fire-resistant silicone composites filled with calcium or aluminium-based material which would meet cable industry specifications, focuses on residues obtained after extreme pyrolysis adapted from the NFC 32070 CR1 French standard. Several methods of analysis (among them ESEM, EDX, XRD, Hg pycnometer, and compression tests) have been carried out in order to investigate the microstructure, volume variation, and compression behaviour of silicone composite residues. Calcium-based fillers produced more cohesive residues than aluminiumbased fillers. Indeed, the co-crystallisation taking place during pyrolysis, as shown in the first part of this series (Hamdani, S. et al., Polym Degrad Stab, 2010, 95, 1911e1919), produced a dense and strong residue. The strong internal porosity and absence of new crystal formation in residues of aluminiumbased filled composites resulted in their low compressive resistance. In addition, water release during the degradation of the latter fillers, favoured residue expansion, high interior porosity and thus weak compression resistance.

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hal-03267707 , version 1 (22-06-2021)

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Siska Hamdani-Devarennes, Audrey Pommier, Claire Longuet, José-Marie Lopez-Cuesta, Francois Ganachaud. Calcium and Aluminium-Based Fillers as Flame-Retardant Additives in Silicone Matrices. II. Analyses on Composite Residues from an Industrial-Based Pyrolysis Test. Polymer Degradation and Stability, 2011, 96, pp.1562-1572. ⟨10.1016/j.polymdegradstab.2011.05.019⟩. ⟨hal-03267707⟩
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